What Is Advanced-N?

Ke Zhuofeng, male, born in October 1980, native of Guangdong, PhD, professor, Ph.D. supervisor, School of Materials Science and Engineering, Sun Yat-sen University.

Ke Zhuofeng

2019-present Sun Yat-sen University, School of Materials Science and Engineering, Professor / PhD Supervisor 2016-2018 Sun Yat-sen University, School of Materials Science and Engineering, Associate Professor / PhD Supervisor 2012-2016 Sun Yat-sen University, School of Chemistry, Associate Professor / PhD Supervisor 2009-2012 Kenichi FIFC Fellow

2005-2009 Sun Yat-sen University / University of North Texas, Physical Chemistry, joint training Ph.D. 2002-2005 Sun Yat-sen University, Polymer Chemistry and Physics, Master 1998-2002 Sun Yat-sen University, Department of Chemistry, undergraduate ^[1]

1. Renewable energy, renewable resources and materials 2. New methods for renewable catalysis and synthesis 3. Precise catalyst design for theoretical calculations ^[1]

Outstanding Youth in Natural Science of Guangdong Province (2015)
Guangdong Special Support Plan 10 Million Project Young Talents (2014)
Kenichi Fukui FIFC Fellow (2009-2012) ^[1]

Ke Zhuofeng Scientific Research Project

National Natural Science Foundation of China, 2017.01-2020.12, Hosting National Natural Science Foundation of China, 2015.01-2018.12, Hosting National Natural Science Foundation of China Youth Project, 2013.01-2015.12, Hosting Guangdong Natural Science Outstanding Youth Fund, 2015.08-2019.08, Hosted the Guangdong Special Support Program for the top ten million engineering young talents, 2015.12-2018.12, hosted the key training project for young teachers of Sun Yat-sen University, 2018.10-2019.12, hosted the Sun Yat-sen University's "hundred-person program" startup project, 2012.4-2013.12, hosted ^[1]

On behalf of Ke Zhuofeng

78. Huang, X., Zhang, KX, Shao YX, Li YW, Gu, FL, Qu L.-B., Zhao, CY, Ke, Zhuofeng *. Mechanism of Si-H Bond Activation for Lewis Acid PBP-Ni Catalyzed Hydrosilylation of CO2: The Role of the Linear SN2 Type Cooperation. ACS Catal. , 2019, 9, 52795289. DOI: 10.1021 / acscatal.9b00879.

77. Huang, M., Li, YK, Li, YW, Liu, JH, Shu, SW, Liu, Y., Ke, Zhuofeng *. Room Temperature N -Heterocyclic Carbene Manganese Catalyzed Selective N -Alkylation of Anilines with Alcohols. Chem. Commun ., 2019, DOI: 10.1039 / C9CC02989C.

76.Xie, HS; Shao, YX; Gui, J .; Lan JY; Lu ZP; Ke, Zhuofeng; * Deng YF; Jiang HF; Zeng W. * Co (II) -Catalyzed Regioselective Pyridine CH Coupling with 2-Diazoacetates Org. Lett. , 2019, 21, 34273430.

75.Ye, ZR; Huang X .; Shao, YX; Jiang, JX; Qu L.-B .; Zhao, CY; Ke, Zhuofeng. * One Catalyst, Multiple Processes: Ligand Effects on Chemoselective Control in Ru Catalyzed anti- Markovnikov Reductive Hydration of Terminal Alkynes. Catal. Sci. Technol. , 2019, 9, 2315 2327.

74.Shu, SW; Huang, MJ; Jiang, JX; Qu L.-B .; Liu Y. *; Ke, Zhuofeng. * Catalyzed or Non-Catalyzed: Chemoselectivity of Ru-Catalyzed Acceptorless Dehydrogenative Coupling of Alcohol and Amine via Metal-Ligand Bond Cooperation and (De) aromatization. Catal. Sci. Technol. , 2019, 9, 2305 2314.

73. Geng, W .; Xiao, JT; Brown JJ; Page, AJ; Ke, Zhuofeng. * New Phosphorene by Phase Combination with Tunable Electronic and Mechanical Properties J. Phys. Chem. C 2019, 123, 1078810794 .

72. Zou, XL, Zhao, HN, Li, YW, Gao, Q., Ke, Zhuofeng *, Xu, SM * Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Asymmetric C (sp2) -H Borylation of Diarylmethylamines. J. Am Chem. Soc . 2019, 141 (13) , 5334.

71. He, TJ, Ye, ZR, Ke, Zhuofeng, Huang, JM * Stereoselective synthesis of sulfur-containing b-enaminonitrile derivatives through electrochemical Csp3-H bond oxidative functionalization of acetonitrile. Nat. Comm ., 2019, 10, 833, DOI: 10.1038 / s41467-019-08762-5

70. Huang, M., Li, YW, Liu, JH, Lan, X.-B., Liu, Y., Zhao, CY, Ke, Zhuofeng *. Bifunctional Strategy to N-Heterocyclic Carbene Stabilized Iridium Complex Catalyzed N- Alkylation of Amines with Alcohols in Aqueous. Green Chem., 2019, 21, 219-224

69. Hou, C., Li, YW, Jiang, JX, Zhao, CY, * Ke, Zhuofeng. * Co (I) and Ni (II) Pincer Complexes Catalyzed Hydrogenation of Ketone: Intriguing Mechanism Dichotomy by Ligand Field Variation. Catal Sci. Technol. , 2019, 9, 125-135.

68. Shu, SW, Li, YW, Jiang, JX, Ke, Zhuofeng, * Liu, Y. * Mechanism of Hypervalent Iodine Promoted Fluorocyclization of Unsaturated Alcohols: Metathesis via Double Acids Activation. J. Org. Chem ., 2019, 84 (1), 458--462.

67. Shao, YX, Zhang, JY, Li YW, Liu, Y., * Ke, Zhuofeng. * Frustrated Lewis Pair Catalyzed CH Activation of Heteroarenes: A Stepwise Carbene Mechanism Due to Distance Effect. Org. Lett. , 2018, 20 , 1102-1105.

66. Xu, X., Chen, X., Shao, YX, Xie, HS, Deng, YF, Ke, Zhuofeng, * Jiang HF, Zeng W. * Co (III) -Catalyzed Coupling-Cyclization of Aryl CH Bonds with a-Diazoketones Involving Wolff Rearrangement. ACS Catal. , 2018, 8, 13081312

65. Zhang, ZH, Li, YW, Hou C., Zhao, CY, Ke, Zhuofeng. * DFT Study of CO2 Hydrogenation Catalyzed by a Cobalt-Base System: an Unexpected Formate Anion Assisted Deprotonation Mechanism. Catal. Sci. Technol. , 2018, 8, 656-666.

64. Xie, HS, Ye, ZR, Ke, Zhuofeng *, Jiang, HF *, Zeng, W. * Rh (III) -catalyzed regioselective intermolecular N-methylene Csp3--H bond carbenoid insertion. Chem. Sci. , 2018, 9, 985-989.

63. Brown, JJ, Ke, Zhuofeng, Geng, W. & Page, AJ Oxygen Vacancy Defect Migration in Titanate Perovskite Surfaces: Effect of the A-Site Cations. J. Phys. Chem. C , 2018, 122, 14590-14597 .

62. Chao, X.-J., Wang, K.-N., Sun, L.-L., Cao, Q. *, Ke, Zhuofeng , Cao, D.-X. & Mao, Z.-W . * Cationic Organochalcogen with Monomer / Excimer Emissions for Dual-Color Live Cell Imaging and Cell Damage Diagnosis. ACS Appl. Mater. Interfaces , 2018, 10, 13264-13273, doi: 10.1021 / acsami.7b12521

61. Xue, Z., Li, Y., Zhang, Y., Geng, W., Jia, B., Tang, J., Bao, S., Wang, H.-P., Fan, Y., Wei, Z.-w., Zhang, Z., Ke, Zhuofeng, Li, G. * & Su, C.-Y. * Modulating Electronic Structure of Metal-Organic Framework for Efficient Electrocatalytic Oxygen Evolution. Advanced Energy Materials , 2018 , 8, 1801564, doi: 10.1002 / aenm.201801564

60. Sun, LL, Shu, SW, Zhou, Y., Hou S., * Liu, Y. and Ke, Zhuofeng. * Regulating the Optoelectronic Properties of Nickel Dithiolene by the Substituents: A Theoretical Study. Materials , 2018, 11 , 2192; doi: 10.3390 / ma11112192

59. Xiao, M., Jiang, J., Zhang, T., Xu, A., Ke, Zhuofeng, * & Hong, L. * Zwitterionic Copolymerization of -Butyrolactone with Styrene. Macromol. Chem. Phys ., 2018 , 219, 1800189, doi: 10.1002 / macp.201800189.

58. Ke, Zhuofeng, * Li, Y., Hou, C. & Liu, Y. Homogeneously catalyzed hydrogenation and dehydrogenation reactions From a mechanistic point of view. Physical Sciences Reviews, 2018, 3, 20170038. Book Chapter of Hydrogen Storage: Based on Hydrogenation and Dehydrogenation Reactions of Small Molecules " (ISBN: 9783110534603)

57. Li, YW, Liu, JH, Hou, C., Shao YX, Qu L.-B., Zhao CY, Ke, Zhuofeng. * Elucidating Metal Hydride Reactivity Using Late Transition Metal Boryl and Borane Hydrides: 2c-2e Terminal Hydride, 3c-2e Bridging Hydride, and 3c-4e Bridging Hydride. Catal. Sci. Technol ., 2018 , 8, 3395-3405

56. Shu SW, Liu, Z., Li, YK, Ke, Zhuofeng, * Liu, Y. * Diastereoselectivity in a cyclic secondary amine catalyzed asymmetric Mannich reaction: a model rationalization from DFT studies. Org. Chem. Front ., 2018 , 5, 2148-2157

55. Shao, Y., Huang, X., Zhao, C. * & Ke, Zhuofeng. * Making more efficient lithium carbenoid reagents for cyclopropanation by hetero-aggregation: A DFT prediction on a new factor to control the SN2-Type organometallic reaction. J. Organomet. Chem. 2018, 864, 110-114. (Invited paper)

54. Zhang, J., Shao, Y., Li, Y., Liu, Y. * & Ke, Zhuofeng. * Rational design of FLP catalysts for reversible H 2 activation: A DFT study of the geometric and electronic effects. Chin Chem. Lett. 2018, 29, 1226-1232. (Invited paper)

53. Wang, J.-W., Hou, C., Huang, H.-H., Liu W.-J., Ke, Zhuofeng, * Lu, T.-B. * Further insight into the electrocatalytic water oxidation by macrocyclic nickel (II) complexes: the influence of steric effect on the catalytic activity. Catal. Sci. Technol. , 2017 , 7, 5585-5593

52. Zhang, JY, Lin, JS, L YW, Shao YX, Huang X., Zhao CY, Ke, Zhuofeng. * The effect of auxiliary ligand on the mechanism and reactivity: DFT study on H2 activation by Lewis acid--transition metal complex (tris (phosphino) borane) Fe (L). Catal. Sci. Technol. , 2017, 7, 4866-4878.

51. Li, Y., Zhang, J., Shu, S., Shao Y., Liu, Y. *, Ke, Zhuofeng, * Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts. C hin. J. Org. Chem . 2017, 37, 2187-2202. (Invited paper)

50. Xiong, B., Jiang, J., Zhang, S., Jiang H., Ke, Zhuofeng, * Zhang M. * Ruthenium-Catalyzed Direct Synthesis of Semisaturated Bicyclic Pyrimidines via Selective Transfer Hydrogenation. Org. Lett. , 2017 , 19 (10), 2730-2733.

49. Xu, Y., Wu, Z., Jiang J., Ke, Zhuofeng, Zhu, C. * Merging Distal Alkynyl Migration and Photoredox Catalysis for Radical Trifluoromethylative Alkynylation of Unactivated Olefins. Angew. Chem., Int. Ed . 2017 , 56, 4545-4548.

48. Lan, X.-B. Li, YW, Li, Y.-F., Shen D.-S., Ke, Zhuofeng *, Liu F.-S. * Flexible Steric Bulky Bis (Imino) acenaphthene (BIAN ) -Supported N-Heterocyclic Carbene Palladium Precatalysts: Catalytic Application in Buchwald--Hartwig Amination in Air. J. Org. Chem . 2017, 82 (6), 2914-2925.

47. Hou, C., Jiang, J., Li, Y., Zhao, C. *, Ke, Zhuofeng *. When Bifunctional Catalyst Encounters Dual MLC Modes: DFT Study on the Mechanistic Preference in Ru-PNNH Pincer Complex Catalyzed Dehydrogenative Coupling Reaction. ACS Catal. 2017, 7 (1), 786795.

46. Xiao X., Hou C., Zhang Z., Ke Zhuofeng *, Lan J., Jiang H., Zeng W. * Iridium (III) -Catalyzed Regioselective Intermolecular Unactivated Secondary Csp3-H Bond Amidation. Angew. Chem. , Int. Ed . 2016, 128, 1207612080.

45. Li, Y., Hou, C., Jiang, J., Zhang, Z., Zhao, C., Page, A., Ke, Zhuofeng *. General H2 Activation Modes for Lewis Acid-Transition Metal Bifunctional Catalysts. ACS Catal. 2016, 6, 1655--1662.

44. Wu, JJ, Li, Y., Zhou, HY, Wen, AH, Lun, CC, Yao, SY, Ke, Zhuofeng *, Ye, BH *. Copper-Catalyzed Carbamoylation of Terminal Alkynes with Formamides via Cross-Dehydrogenative Coupling. ACS Catal. 2016, 6, 12631267.

43. Hou C., Zhang Z., Zhao, C. *, Ke Zhuofeng *. DFT Study of Acceptorless Alcohol Dehydrogenation Mediated by Ruthenium Pincer Complexes: Ligand Tautomerization Governing Metal Ligand Cooperation. Inorg. Chem. 2016, 55, 65396551 .

42. Wei J., Jiang J., Xiao X., Lin DG *, Deng Y., Ke, Zhuofeng *, Jiang HF, Zeng, W *. Copper-Catalyzed Regioselective CH Sulfonylation of 8-Aminoquinolines. J. Org. Chem. 2016, 81 (3), 946--955.

41. Ouyang, J.-S., Li, Y.-F., Shen D.-S., Ke, Zhuofeng *, Liu F.-S. * Bulky -diimine palladium complexes: highly efficient for direct C H bond arylation of heteroarenes under aerobic conditions dimine arylation. Dalton Trans . 2016, 45, 1491914927.

40. He, X.-X., Li Y., Ma B.-B., Ke Zhuofeng *, Liu F.-S. * Sterically Encumbered Tetraarylimidazolium Carbene Pd-PEPPSI Complexes: Highly Efficient Direct Arylation of Imidazoles with Aryl Bromides under Aerobic Conditions. Organometallics , 2016, 35, 26552663.

39. Peng, C.-C., Li, Z., Deng, L.-Q., Ke, Zhuo-Feng, Chen, W.-H. 2,6-Bis (benzimidazol-2-yl) pyridine as a potent transmembrane anion transporter. Bioorg. Med. Chem. Lett. 2016, 26, 24422445.

38. Xu, H., Zhang, X., Ke, Zhuofeng *, Zhao, C. * A Theoretical Study of Dirhodium-Catalyzed Intramolecular Aliphatic C? H Bond Amination of Aryl Azides. RSC Adv. 2016, 6, 2904529053 .

37. Xue, S.-S .; Zhao, M .; Ke, Zhuo-Feng; Cheng, B.-C .; Su, H .; Cao, Q .; Cao, Z.-K .; Wang, J .; Ji, L.-N .; Mao, Z.-W. Enantioselective Hydrolysis of Amino Acid Esters Promoted by Bis (-cyclodextrin) Copper Complexes. Sci. Rep., 2016, 6, DOI: 10.1038 / srep22080.

36. Jiang, J., Liu, Y., Hou, C., Li, Y., Luan, Z., Zhao C., and Ke, Zhuofeng *. Rationalization of the Selectivity between 1,3- and 1,2 -Migration: DFT Study on Gold (I) -Catalyzed Propargylic Ester Rearrangement. Org. Biomol. Chem ., 2016, 14, 35583563.

35. Luo, B.-T., Liu H., Lin Z.-J., Jiang, J., Sheng D.-S., Liu R.-Z., Ke, Zhuofeng *, Liu, F.- S. * Aerobic and Efficient Direct Arylation of Five-Membered Heteroarenes and Their Benzocondensed Derivatives with Aryl Bromides by Bulky -Hydroxyimine Palladium Complexes. Organometallics , 2015, 34, 48814894.

34. Hou, C., Jiang, J., Li, Y., Zhang, Z., Zhao C. *, Ke, Zhuofeng *. Unusual Non-bifunctional Mechanism for Co-PNP Complex Catalyzed Transfer Hydrogenation Governed by the Electronic Configuration of Metal Center. Dalton Trans . 2015, 44, 1657316585.

33. Chung, LW, Sameera, WMC, Ramozzi, R., Page, AJ, Hatanaka, M., Petrova, GP, Harris, TV, Li X., Ke, Zhuofeng, Liu, F., Li, H.- B., Ding, L., Morokuma, K. * The ONIOM Method and Its Applications. Chem. Rev. 2015, 15, 5678-5796.

32. Xu, X.-Y., Li, J., Zhang, X., Xu, H., Ke, Zhuo-Feng *, Zhao, C. * Removal of NO with silicene: A DFT investigation. RSC Adv. 2015, 5, 22135--22147.

31. Jiang, J., Hou, C., Zhang S., Luan Z., Zhao, C., Ke, Zhuofeng. * The Effect of HSAB on Stereoselectivity: Copper and Gold Catalyzed 1,3-Phosphatyloxy and 1,3 -Halogen Migration Relay to 1,3-Dienes. J. Org. Chem. 2015, 80 (3), 16611671.

30. Zhang, F., Fan, J., Yu, H., Ke, Zhuofeng, Nie, C., Kuang, D. *, Shago, G. *, Su C. Nonplanar Organic Sensitizers Featuring a Tetraphenylethene Structure and Double Electron-Withdrawing Anchoring Groups. J. Org. Chem. 2015, 80, 90349040.

29. Zhang, M., Zhang, M.-T., Hou, C., Ke, Zhuofeng *, Lu T.-B. * Homogeneous Electrocatalytic Water Oxidation at Neutral pH by a Robust Macrocyclic Nickel (II) Complex. Angew Chem., Int. Ed. 2014, 53, 1304213048. (Frontispiece Paper)

28. Hou, C., Jiang J., Zhang S., Wang G., Zhang Z., Ke, Zhuofeng *, Zhao C. * Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanism and Metal Effect. ACS Catal. 2014, 4, 29902997.

27. Zhou, YG, Zhang, XP, Liang, HY, Cao, ZK, Zhao, XY, He, YW, Wang, SL, Pang, JY, Zhou, ZY, Ke, Zhuofeng *, Qiu LQ * Enantioselective Synthesis of Axially Chiral Biaryl Monophosphine Oxides via Direct Asymmetric Suzuki Coupling and DFT Investigations of the Enantioselectivity. ACS Catal. 2014, 4, 13901397.

26. Petrova, GP, Ke, Zhuofeng, Park S., Sugiyama H., Morokum K. * The origin of enantioselectivity for intramolecular Friedel--Crafts reaction catalyzed by supramolecular Cu / DNA catalyst complex. Chem. Phys. Lett . 2014, 600 , 87--95.

25. Zhang, X., Ke, Zhuofeng, DeYonker NJ, Xu, H., Li Z.-F., Xu X., Zhang X., Su C.-Y., Phillips DL, Zhao C. * Mechanism and Enantioselectivity of Dirhodium-Catalyzed Intramolecular C--H Amination of Sulfamate. J. Org. Chem. 2013, 78 (24), 12460--12468.

24. Liu, Y., Ma, L., Chen, W.-H. *, Park, H., Ke, Zhuofeng *, Wang, B *. Binding Mechanism and Synergetic Effects of Xanthone Derivatives as Noncompetitive -Glucosidase Inhibitors : A Theoretical and Experimental Study. J. Phys. Chem. B 2013, 117 (43), 1346413471.

23. Ye, R.-R., Ke, Zhuofeng, Tan, C.-P., He, L., Ji, L.-N. & Mao, Z.-W. Histone-Deacetylase-Targeted Fluorescent Ruthenium ( II) Polypyridyl Complexes as Potent Anticancer Agents. Chem. Eur. J. 2013, 19 (31), 10160 10169. (Cover Page)

22. Xu, HY, Zhang, XT, Ke, Zhuofeng, Li, ZF, Xu, XY, Su, CY, Phillips, DL & Zhao, CY Density functional theory study of the mechanism of zinc carbenoid promoted cyclopropanation of allenamides. RSC Adv . 2013, 3, 1713117142.

21. Ke, Zhuofeng, Abe, S., Ueno, T., & Morokuma, Keiji. Catalytic Mechanism in Artificial Metalloenzyme: QM / MM Study of Phenylacetylene Polymerization by Rhodium Complex Encapsulated in apo-Ferritin. J. Am. Chem. Soc . 2012, 134 (37), 15418--15429.

20. Ke, Zhuofeng, Abe, S., Ueno, T., & Morokuma, Keiji. Rh-catalyzed Polymerization of Phenylacetylene: Theoretical Studies of the Reaction Mechanism, Regioselectivity and Stereoregularity. J. Am. Chem. Soc. 2011, 133 (20), 79267941. (JACS beta Select issue 13)

19. Liu, Y., Ke, Zhuofeng, Liu, Shuwen, Chen, Wen-Hua, Jiang, Shibo; Jiang, Zhi-Hong. An Amphiphilic Conjugate Approach toward the Design and Synthesis of Betulinic Acid-Polyphenol Conjugates as Inhibitors of the HIV-1 gp41 Fusion Core Formation. ChemMedChem 2011, 6 (9), 16541664.

18. Gao, H., Ke, Zhuofeng, DeYonker NJ, Wang J., Xu H., Mao Z.-W., Phillips, DL, Zhao C., Dinuclear Zn (II) Complex Catalyzed Phosphodiester Cleavage Proceeds via a Concerted Mechanism: A Density Functional Theory Study. J. Am. Chem. Soc. 2011, 133 (9), 29042915.

17. Ke, Zhuofeng & Cundari, TR, Palladium-Catalyzed CH Activation / CN Bond Formation Reactions: DFT Study of Reaction Mechanisms and Reactive Intermediates. Organometallics 2010, 29 (4), 821834. (Top10 Most Accessed Articles of Organometallics in 2010)

16. Lee, JP, Ke, Zhuofeng, Ramirez, MA, Gunnoe, TB, Cundari, TR, Boyle, PD, & Petersen, JL, Six-, Five-, and Four-Coordinate Ruthenium (II) Hydride Complexes Supported by N -Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity, and Catalytic Hydrogenation of Olefins, Aldehydes, and Ketones. Organometallics 2009, 28 (6), 17581775.

15. Guo, Z., Xue, JD, Ke, Zhuofeng, Phillips, DL, & Zhao, CY, Influence of Water Hydrogen Bonding on the Reactions of Arylnitrenium Ions With Guanosine: Hydrogen-Bonding Effects Can Favor Reaction at the C8 Site. J. Phys. Chem. B 2009, 113 (18), 6528--6532.

14. Foley, NA, Lee, JP, Ke, Zhuofeng, Gunnoe, TB, & Cundari, TR, Ru (II) Catalysts Supported by Hydridotris (pyrazolyl) borate for the Hydroarylation of Olefins: Reaction Scope, Mechanistic Studies, and Guides for the Development of Improved Catalysts. Acc. Chem. Res. 2009, 42 (5), 585597.

13. Liu, Y., Ke, Zhuofeng, Cui, JF, Chen, WH, Ma, L., & Wang, B., Synthesis, inhibitory activities, and QSAR study of xanthone derivatives as alpha-glucosidase inhibitors. Bioorg. Med Chem . 2008, 16 (15), 7185-7192.

12. Guo, Z., Ke, Zhuofeng, Phillips, DL, & Zhao, CY, Intrinsic reaction coordinate analysis of the activation of CH4 by molybdenum atoms: A density functional theory study of the crossing seams of the potential energy surfaces. Organometallics 2008 , 27 (2), 181--188.

11. Foley, NA, Ke, Zhuofeng, Gunnoe, TB, Cundari, TR, & Petersen, JL, Aromatic CH activation and catalytic hydrophenylation of ethylene by TpRu {P (OCH2) (3) CEt} (NCMe) Ph. Organometallics 2008 , 27 (13), 3007--3017.

10. Lin, XF, Zhao, CY, Che, CM, Ke, Zhuofeng, & Phillips, DL, A DFT study on the mechanism of Rh-2 (II, II) -catalyzed intramolecular amidation of carbamates. Chem. Asian J. 2007, 2 (9), 1101--1108.

9. Ke, Zhuofeng, Zhou, YB, Gao, H., Zhao, CY, & Phillips, DL, On the mechanism and stereochemistry of chiral lithium-carbenoid-promoted cyclopropanation reactions. Chem. Eur. J. 2007, 13 (23 ), 6724--6731.

8. Ke, Zhuofeng, Zhao, CY, & Phillips, DL, Methylene transfer or carbometalation? A theoretical study to determine the mechanism of lithium carbenoid-promoted cyclopropanation reactions in aggregation and solvation states. J. Org. Chem. 2007, 72 ( 3), 848--860.

7. Gao, HY, Ke, Zhuofeng, Pei, LX, Song, KM, & Wu, Q., Drastic ligand electronic effect on anilido-imino nickel catalysts toward ethylene polymerization. Polymer 2007, 48 (25), 72497254.

6. Fang, R., Ke, Zhuofeng, Shen, Y., Zhao, CY, & Phillips, DL, Concurrent cyclopropanation by carbenes and carbanions? A density functional theory study on the reaction pathways. J. Org. Chem. 2007, 72 (14), 5139-5145.

5. Zhou, YB, Ke, Zhuofeng, & Zhao, CY, A theoretical study on the mechanism of ruthenium (II) -catalyzed reaction of organic azide with alkyne. Acta Chim. Sin . 2006, 64 (20), 20712078 .

4. Zhang, JK, Ke, Zhuofeng, Bao, F., Long, JM, Gao, HY, Zhu, FM, & Wu, Q., Ethylene polymerization and oligomerization catalyzed by bulky beta-diketiminato Ni (II) and beta- diimine Ni (II) complexes / methylaluminoxane systems. J. Mol. Catal. A: Chem 2006, 249 (1-2), 3139.

3. Ye, GD, Ke, Zhuofeng, Yan, JW, Zhao, TY, Zeng, ZH, & Chen, YL, Low VOC bifunctional photoinitiator based on alpha-hydroxyalkylphenone structure. Polymer 2006, 47 (13), 46034612.

2. Li, ZH, Ke, Zhuofeng, Zhao, CY, Geng, ZY, Wang, YC, & Phillips, DL, A density functional theory study of aluminum carbenoid (CH3) (2) AlCH2X (X = Cl, Br, I ) promoted cyclopropanation reactions compared to IMCH2I (M = Li, Sm, Zn) carbenoids. Organometallics 2006, 25 (15), 37353742.

1. Zhang, JK, Gao, HY, Ke, Zhuofeng, Bao, F., Zhu, FM, & Wu, Q., Investigation of 1-hexene isomerization and oligomerization catalyzed with beta-diketiminato Ni (II) bromide complexes / methylaluminoxane system. J. Mol. Catal. A: Chem 2006, 231 (1-2), 2734 ^[1]

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