What is Alloy Tubing?
Alloy pipe is a type of seamless steel pipe. Its performance is much higher than that of ordinary seamless steel pipes, because this steel pipe contains more Cr, and its high temperature, low temperature and corrosion resistance are other The seam steel pipe is incomparable, so the alloy pipe is widely used in petroleum, aerospace, chemical, power, boiler, military and other industries.
Alloy tube
Alloy pipe is
Alloy pipe is a type of seamless steel pipe. Alloy pipes are divided into structural seamless pipes and high-pressure heat-resistant alloy pipes. Mainly different from the production standards and industry of alloy pipes, annealing and tempering of alloy pipes change its mechanical properties. To achieve the required processing conditions. Its performance is higher than that of ordinary seamless steel pipes. It has higher variability utilization value, alloy pipe contains more Cr in chemical composition, and has high temperature resistance, low temperature resistance and corrosion resistance. Ordinary carbon seamless pipes do not contain alloy components or have very few alloy components. The reason why alloy pipes are widely used in petroleum, aerospace, chemical, power, boiler, military, and other industries is because the mechanical properties of alloy pipes change and adjust well.
standard | Grade | Tensile strength (MPa) | Yield strength (MPa) | Elongation(%) | hardness |
GB3087 | 10 | 335 475 | 195 | 24 | / |
20 | 410 550 | 245 | 20 | / | |
GB5310 | 20G | 410 550 | 245 | 24 | / |
20MnG | 415 | 240 | 22 | / | |
25MnG | 485 | 275 | 20 | / | |
15CrMoG | 440 640 | 235 | 21 | / | |
12Cr2MoG | 450 600 | 280 | 20 | / | |
12Cr1MoVG | 470 640 | 255 | 21 | / | |
12Cr2MoWVTiB | 540 735 | 345 | 18 | / | |
10Cr9Mo1VNb | 585 | 415 | 20 | / | |
ASME SA210 | SA210A-1 | 415 | 255 | 30 | 143HB |
SA210C | 485 | 275 | 30 | 179HB | |
ASME SA213 | SA213 T11 | 415 | 205 | 30 | 163HB |
SA213 T12 | 415 | 220 | 30 | 163HB | |
SA213 T22 | 415 | 205 | 30 | 163HB | |
SA213 T23 | 510 | 400 | 20 | 220HB | |
SA213 T91 | 585 | 415 | 20 | 250HB | |
SA213 T92 | 620 | 440 | 20 | 250HB | |
DIN17175 | ST45.8 / | 410 530 | 255 | 21 | / |
15Mo3 | 450 600 | 270 | 22 | / | |
13CrMo44 | 440 590 | 290 | 22 | / | |
10CrMo910 | 480 630 | 280 | 20 | / | |
standard | Grade | chemical composition(%) | | | | | | | | | | | | | | |
C | Si | Mn | P | S | Cr | Mo | Cu | Ni | V | Al | W | Ti | Nb | N | | |
GB3087 | 10 | 0.07 0.13 | 0.17 0.37 | 0.38 0.65 | 0.030 | 0.030 | 0.3 0.65 | / | 0.25 | 0.30 | / | / | | | | |
20 | 0.17 0.23 | 0.17 0.37 | 0.38 0.65 | 0.030 | 0.030 | 0.3 0.65 | / | 0.25 | 0.30 | / | / | | | | | |
GB5310 | 20G | 0.17 0.24 | 0.17 0.37 | 0.35 0.65 | 0.030 | 0.030 | 0.25 | 0.15 | 0.20 | 0.25 | 0.08 | | | | | |
20MnG | 0.17 0.24 | 0.17 0.37 | 0.70 1.00 | 0.030 | 0.030 | 0.25 | 0.15 | 0.20 | 0.25 | 0.08 | | | | | | |
25MnG | 0.18 0.24 | 0.17 0.37 | 0.80 1.10 | 0.030 | 0.030 | 0.25 | 0.15 | 0.20 | 0.25 | 0.08 | | | | | | |
15CrMo | 0.12 0.18 | 0.17 0.37 | 0.40 0.70 | 0.030 | 0.030 | 0.80 1.10 | 0.40 0.55 | 0.20 | 0.30 | | | | | | | |
12Cr2MoG | 0.08 0.15 | 0.50 | 0.40 0.70 | 0.030 | 0.030 | 2.00 2.50 | 0.90 1.20 | 0.20 | 0.30 | | | | | | | |
12Cr1MoV | 0.08 0.15 | 0.17 0.37 | 0.40 0.70 | 0.030 | 0.030 | 0.90 1.20 | 0.25 0.35 | 0.20 | 0.30 | 0.15 0.30 | | | | | | |
12Cr2MoWVTiB | 0.08 0.15 | 0.45 0.75 | 0.45 0.65 | 0.030 | 0.030 | 1.60 2.10 | 0.50 0.65 | 0.20 | 0.30 | 0.28 0.42 | | 0.30 0.55 | 0.08 0.15 | B 0.002 0.008 | | |
10Cr9Mo1VNb | 0.08 0.12 | 0.20 0.50 | 0.30 0.60 | 0.020 | 0.010 | 8.00 9.50 | 0.85 1.05 | 0.20 | 0.40 | 0.18 0.25 | 0.015 | | | 0.06 0.10 | 0.03 0.07 | |
ASME SA210 | SA210A-1 | 0.13 0.19 | 0.1 | 0.45 0.65 | 0.030 | 0.030 | | | | | | | | | | |
SA210C | 0.18 0.24 | 0.1 | 0.80 1.10 | 0.030 | 0.030 | | | | | | | | | | | |
ASME SA213 | SA213 T11 | 0.05 0.15 | 0.50 1.0 | 0.30 0.60 | 0.030 | 0.030 | 1.00 1.50 | 0.50 1.00 | | | | | | | | |
SA213 T12 | 0.05 0.15 | 0.50 | 0.30 0.61 | 0.030 | 0.030 | 0.80 1.25 | 0.44 0.65 | | | | | | | | | |
SA213 T22 | 0.05 0.15 | 0.50 | 0.30 0.60 | 0.030 | 0.010 | 1.90 2.60 | 0.87 1.13 | | | | | | | | | |
SA213 T23 | 0.04 0.10 | 0.50 | 0.10 0.60 | 0.030 | 0.030 | 1.90 2.60 | 0.05 0.30 | | | | 0.030 | 1.45 1.75 | B 0.0005 0.006 | 0.02 0.08 | 0.040 | |
SA213 T91 | 0.08 0.12 | 0.20 0.50 | 0.30 0.60 | 0.020 | 0.010 | 8.00 9.50 | 0.85 1.05 | | 0.40 | 0.18 0.25 | 0.015 | | | 0.06 0.10 | 0.03 0.07 | |
SA213 T92 | 0.07 0.13 | 0.50 | 0.30 0.60 | 0.020 | 0.010 | 8.50 9.50 | 0.30 0.60 | | 0.40 | 0.15 0.25 | 0.015 | 1.50 2.00 | B 0.001 0.006 | 0.04 0.09 | 0.03 0.07 | |
DIN 17175 | ST45.8 / | 0.21 | 0.10 0.35 | 0.40 1.20 | 0.040 | 0.040 | | | | | | | | | | |
15Mo3 | 0.12 0.20 | 0.10 0.35 | 0.40 0.80 | 0.035 | 0.035 | | 0.25 0.35 | | | | | | | | | |
13CrMo44 | 0.10 0.18 | 0.10 0.35 | 0.40 0.70 | 0.035 | 0.035 | 0.70 1.10 | 0.45 0.65 | | | | | | | | | |
10CrMo910 | 0.08 0.15 | 0.50 | 0.30 0.70 | 0.025 | 0.020 | 2.00 2.50 | 0.90 1.10 | 0.30 | 0.30 | | 0.015 | | | | | |
Alloy management theory calculation:
(Outer diameter-wall thickness) * wall thickness * 0.02483 = weight per meter.
The material of the alloy tube is roughly : 16-50Mn, 27SiMn, 20-40Cr, 12-42CrMo
16Mn 12Cr1MoV T91 27SiMn 30CrMo 15CrMo 20G Cr9Mo 10CrMo910 15Mo3 15CrMoV 35CrMoV 45CrMo
Classification of alloy pipes:
Palladium alloy tube is used to separate hydrogen from impurities.
The principle of palladium tube purification of hydrogen is that when hydrogen to be purified is passed to one side of the palladium tube at 300-500 ° C, hydrogen is adsorbed on the wall of the palladium tube. Because the 4d electron layer of palladium lacks two electrons, It can form unstable chemical bonds with hydrogen (this reaction of palladium and hydrogen is reversible). Under the action of palladium, hydrogen is ionized into protons with a radius of 1.5 × 1015m, and the lattice constant of palladium is 3.88 × 10 10m (at 20 ° C), so it can pass through the palladium tube, under the action of palladium, the protons combine with the electrons again to form hydrogen molecules, and escape from the other side of the palladium tube. On the surface of the palladium tube, the undissociated gas is impermeable, so high purity hydrogen can be obtained by using the palladium tube. Although palladium has a unique permeability to hydrogen,
[1] To reduce the amount of hydrogen permeation in T22 alloy steel pipes, it is necessary to minimize the pickling of high-strength / high-hardness steel T22 alloy steel pipes because pickling can increase hydrogen embrittlement. When removing rust and scale, try to use sand blasting. If the T22 alloy steel pipe with Rockwell hardness equal to or greater than HRC 32 is pickled, you must ensure that the T22 alloy steel pipe is soaked in acid when the pickling process is formulated The maximum time is 10 minutes. The concentration of the acid solution should be reduced as much as possible, and the parts should be immersed in acid for less than 10 minutes. When removing oil, use chemical degreasing methods such as detergent or solvent degreasing to reduce the amount of hydrogen penetration. If electricity is used, Chemical degreasing, cathode first, anode first, high strength T22 alloy steel pipe is not allowed to use the cathode for degreasing; strictly control the dripping amount of methanol and propane during heat treatment; alkaline plating solution or high current efficiency The amount of liquid hydrogen permeation is small.
[2] Using a coating with low hydrogen diffusivity and low hydrogen solubility is generally believed that when plating Cr, Zn, Cd, Ni, Sn, Pb, hydrogen that penetrates into steel parts is easy to remain, while Cu, Mo, Al, The coatings of T22 alloy steel pipes such as Ag, Au, W have low hydrogen diffusion and low hydrogen solubility, and less hydrogen permeation. In the case of meeting the technical requirements of the product, coatings that do not cause hydrogen permeation, such as mechanical zinc plating or chromium-free zinc-aluminum coating, can be used without hydrogen embrittlement, high corrosion resistance, good adhesion, and Environmental protection.
[3] Remove stress before plating and remove hydrogen after plating to eliminate the hidden danger of hydrogen embrittlement. If the internal residual stress is large after quenching, welding and other processes, tempering should be performed before plating. Tempering can reduce the stress in the part. The number of traps, thereby mitigating the hidden dangers of hydrogen embrittlement.
[4] Control the thickness of the plating layer. As the plating layer covers the surface of the fastener, the plating layer acts as a hydrogen diffusion barrier to a certain extent, which will hinder the diffusion of hydrogen to the outside of the fastener. When the thickness of the coating exceeds 2.5 m, it is very difficult for hydrogen to diffuse out of the fastener. Therefore, the coating thickness of fasteners with a hardness of less than 32HRC can be required to be 12m; for high-strength bolts with a hardness of 32HRC, the coating thickness should be controlled at 8mmax. This requires that in product design, the risk of hydrogen embrittlement of high-strength bolts must be taken into account, and the plating type should be selected reasonably.
First: rust removal level, for epoxy commonly used in alloy pipes,
Classification of alloy pipes
(1)
Deviation level | Standardized outside diameter tolerance |
D1 | ± 1.5% , minimum ± 0.75 mm |
D2 | ± 1.0% . ± 0.50 mm |
D3 | ± 0.75% ± 0.30 mm |
D4 | ± 0.50% . ± 0.10 mm |
Alloy tube is mainly used for heating surface tubes of low and medium pressure boilers (working pressure is generally not greater than 5.88Mpa and working temperature below 450 ° C); for high pressure boilers (working pressure is generally above 9.8Mpa and working temperature is 450 650) ) heating surface pipes, economizers, superheaters, reheaters, pipes for petrochemical industry, etc.
High-pressure alloy tube grades: 15CrMoG, 12Cr2MoG, 12Cr1MoVG, 12Cr2MoWVTiB, 10Cr9Mo1VNb, SA210A1, SA210C, SA213 T11, SA213 T12, SA213 T22, SA213 T23, SA213 T91, SA213 T92, ST45.8 / , 15Mo3, 13CrMo44, 10Cr
Alloy specification table
Unit: Kg / m | | | | | | | |
Wall thickness outer diameter | 3 | 3.5 | 4 | 4.5 | 5 | 5.5 | 6 |
32 | 2.146 | 2.460 | 2.762 | 3.052 | 3.329 | 3.594 | 3.847 |
38 | 2.589 | 2.978 | 3.354 | 3.718 | 4.069 | 4.408 | 4.735 |
42 | 2.885 | 3.323 | 3.749 | 4.162 | 4.562 | 4.951 | 5.327 |
45 | 3.107 | 3.582 | 4.044 | 4.495 | 4.932 | 5.358 | 5.771 |
50 | 3.477 | 4.014 | 4.538 | 5.049 | 5.549 | 6.036 | 6.511 |
54 | 3.773 | 4.359 | 4.932 | 5.493 | 6.042 | 6.578 | 7.103 |
57 | 3.995 | 4.618 | 5.228 | 5.826 | 6.412 | 6.985 | 7.546 |
60 | 4.217 | 4.877 | 5.524 | 6.159 | 6.782 | 7.392 | 7.990 |
63.5 | 4.476 | 5.179 | 5.869 | 6.548 | 7.214 | 7.867 | 8.508 |
68 | 4.809 | 5.567 | 6.313 | 7.047 | 7.768 | 8.477 | 9.174 |
70 | 4.957 | 5.740 | 6.511 | 7.269 | 8.015 | 8.749 | 9.470 |
73 | 5.179 | 5.999 | 6.807 | 7.602 | 8.385 | 9.156 | 9.914 |
76 | 5.401 | 6.258 | 7.103 | 7.935 | 8.755 | 9.563 | 10.358 |
89 | 6.363 | 7.380 | 8.385 | 9.378 | 10.358 | 11.326 | 12.281 |
108 | 7.768 | 9.020 | 10.259 | 11.486 | 12.701 | 13.903 | 15.093 |
133 | 11.178 | 12.725 | 14.261 | 15.783 | 17.294 | 18.792 | |
159 | 13.422 | 15.290 | 17.146 | 18.989 | 20.821 | 22.639 | |
219 | 18.601 | 21.209 | 23.805 | 26.388 | 28.959 | 31.517 | |
273 | 23.262 | 26.536 | 29.797 | 33.046 | 36.283 | 39.508 | |
325 | 27.750 | 31.665 | 35.568 | 39.458 | 43.337 | 47.202 | |
355 | 38.897 | 43.158 | 47.406 | 51.641 | | | |
377 | 41.339 | 45.871 | 50.390 | 54.897 | | | |
426 | 46.777 | 51.913 | 57.036 | 62.147 | | | |
450 | | | | | | | |
480 | | | | | | | |
530 | | | | | | | |
630 | | | | | | | |
Unit: Kg / m | | | | | | | |
Wall thickness outer diameter | 6.5 | 7 | 8 | 8.5 | 9 | 10 | 12 |
32 | 4.088 | | | | | | |
38 | 5.049 | | | | | | |
42 | 5.691 | | | | | | |
45 | 6.172 | | | | | | |
50 | 6.973 | 7.423 | 8.286 | 8.699 | | | |
54 | 7.614 | 8.114 | 9.075 | 9.538 | | | |
57 | 8.095 | 8.632 | 9.667 | 10.167 | | | |
60 | 8.576 | 9.149 | 10.259 | 10.796 | | | |
63.5 | 9.137 | 9.754 | 10.950 | 11.529 | | | |
68 | 9.858 | 10.530 | 11.838 | 12.473 | | | |
70 | 10.179 | 10.876 | 12.232 | 12.892 | 13.539 | 14.797 | 17.164 |
73 | 10.660 | 11.394 | 12.824 | 13.521 | 14.205 | 15.537 | 18.052 |
76 | 11.141 | 11.912 | 13.416 | 14.150 | 14.871 | 16.277 | 18.940 |
89 | 13.225 | 14.156 | 15.981 | 16.875 | 17.756 | 19.483 | 22.787 |
108 | 16.270 | 17.436 | 19.729 | 20.858 | 21.973 | 24.168 | 28.410 |
133 | 20.278 | 21.751 | 24.662 | 26.098 | 27.522 | 30.334 | 35.809 |
159 | 24.446 | 26.240 | 29.791 | 31.548 | 33.293 | 36.746 | 43.503 |
219 | 34.064 | 36.598 | 41.629 | 44.126 | 46.610 | 51.543 | 61.259 |
273 | 42.720 | 45.920 | 52.283 | 55.445 | 58.596 | 64.860 | 77.240 |
325 | 51.056 | 54.897 | 62.542 | 66.346 | 70.137 | 77.684 | 92.629 |
355 | 55.865 | 60.076 | 68.460 | 72.634 | 76.796 | 85.082 | 101.507 |
377 | 59.391 | 63.873 | 72.801 | 77.246 | 81.679 | 90.508 | 108.018 |
426 | 67.246 | 72.332 | 82.468 | 87.518 | 92.555 | 102.592 | 122.519 |
450 | 71.093 | 76.475 | 87.203 | 92.549 | 97.882 | 108.511 | 129.621 |
480 | 75.902 | 81.654 | 93.122 | 98.837 | 104.540 | 115.909 | 138.499 |
530 | 83.917 | 90.286 | 102.987 | 109.319 | 115.638 | 128.240 | 153.296 |
630 | 99.947 | 107.549 | 122.716 | 130.281 | 137.833 | 152.902 | 182 |
16Mn Specification Sheet
specification | Quantity | specification | Quantity | specification | Quantity | specification | Quantity | specification | Quantity | specification | Quantity |
406 * 16 | 12 | 457 * 32 | 20 | 508 * 80 | 20 | 530 * 22 | 10 | 660 * 80 | 20 | 820 * 55 | 56 |
406 * 17 | 14 | 457 * 35 | 25 | 508 * 90 | 20 | 530 * 25 | 20 | 660 * 90 | 20 | 820 * 60 | 52 |
406 * 18 | 14 | 457 * 40 | 20 | 508 * 100 | 20 | 530 * 28 | 15 | 660 * 100 | 20 | 820 * 70 | 54 |
406 * 19 | 14 | 457 * 45 | 25 | 530 * 16 | 30 | 610 * 30 | 20 | 660 * 150 | 20 | 820 * 80 | 50 |
406 * 20 | 14 | 457 * 50 | 15 | 530 * 17 | 20 | 610 * 32 | 10 | 710 * 20 | 30 | 820 * 90 | 65 |
406 * 22 | 14 | 457 * 55 | 20 | 530 * 18 | 20 | 610 * 35 | 10 | 710 * 22 | 15 | 820 * 100 | 62 |
406 * 25 | 18 | 457 * 60 | 20 | 530 * 19 | 20 | 610 * 40 | 10 | 710 * 25 | 20 | 820 * 150 | 61 |
406 * 28 | 20 | 457 * 65 | 15 | 530 * 20 | 30 | 610 * 45 | 10 | 710 * 28 | 15 | 820 * 200 | 63 |
406 * 30 | 25 | 457 * 70 | 20 | 530 * 22 | 20 | 610 * 50 | 20 | 710 * 30 | 20 | 864 * 40 | 75 |
406 * 32 | 25 | 457 * 80 | 20 | 530 * 25 | 30 | 610 * 55 | 15 | 710 * 32 | 15 | 864 * 55 | 78 |
406 * 35 | 25 | 457 * 90 | 25 | 530 * 28 | 30 | 610 * 60 | 15 | 710 * 35 | 15 | 864 * 60 | 79 |
406 * 40 | 25 | 457 * 100 | 20 | 530 * 30 | 20 | 610 * 65 | 10 | 710 * 40 | 20 | 864 * 70 | 81 |
406 * 45 | 50 | 480 * 16 | 50 | 530 * 32 | 30 | 610 * 70 | 60 | 710 * 45 | 20 | 864 * 80 | 89 |
406 * 50 | 28 | 480 * 17 | 15 | 530 * 35 | 20 | 610 * 80 | 10 | 710 * 50 | 20 | 864 * 90 | 85 |
406 * 55 | 25 | 480 * 18 | 15 | 530 * 40 | 20 | 610 * 90 | 10 | 710 * 55 | 15 | 864 * 100 | 25 |
406 * 60 | 20 | 480 * 19 | 30 | 530 * 45 | 20 | 610 * 100 | 15 | 710 * 60 | 25 | 864 * 150 | 36 |
406 * 65 | 25 | 480 * 20 | 20 | 530 * 50 | 20 | 610 * 150 | 15 | 710 * 65 | 30 | 864 * 200 | twenty three |
406 * 70 | 20 | 480 * 22 | 20 | 530 * 55 | 25 | 630 * 18 | 15 | 710 * 70 | 60 | 900 * 60 | 68 |
406 * 80 | 25 | 480 * 25 | 20 | 530 * 60 | 25 | 630 * 19 | 15 | 710 * 80 | 30 | 900 * 70 | twenty three |
406 * 90 | 20 | 480 * 28 | 20 | 530 * 65 | 60 | 630 * 20 | 10 | 710 * 90 | 30 | 900 * 80 | 35 |
426 * 16 | 25 | 480 * 30 | 25 | 530 * 70 | 30 | 630 * 22 | 25 | 710 * 100 | 54 | 900 * 90 | 39 |
426 * 17 | 25 | 480 * 32 | 15 | 530 * 80 | 60 | 630 * 25 | 15 | 710 * 150 | 50 | 900 * 100 | 69 |
426 * 18 | 20 | 480 * 35 | 15 | 530 * 90 | 30 | 630 * 28 | 15 | 720 * 25 | 65 | 900 * 150 | 80 |
use
Alloy steel pipe is mainly used in power plants, nuclear power, high-pressure boilers, high-temperature superheaters and reheaters, and other high-pressure and high-temperature pipes and equipment. , Hot rolled (extruded, expanded) or cold rolled (drawn).
advantage
It can be 100% recycled, in line with the national strategy of environmental protection, energy saving and resource conservation. National policies encourage the expansion of the application field of high-pressure alloy pipes. At present, the proportion of alloy pipe consumption in China's total steel is only half of that in developed countries. The expansion of the field of alloy pipe provides a wider space for industry development. According to the research by the expert group of the Alloy Pipe Branch of the China Special Steel Association, the future annual demand for high-pressure alloy pipe long products in China will reach 10-12%.
Connections and differences with seamless pipes
Alloy pipe is defined according to the production materials (that is, materials), as the name implies, is made of alloy; seamless pipe is defined according to the production process (seamless seamless), which is different from seamless pipe is Slotted pipe, including straight seam welded pipe and spiral welded pipe.
standard
Alloy pipes have a hollow cross section and are widely used as pipelines for transporting fluids, such as pipelines for transporting oil, natural gas, gas, water, machinery, and certain solid materials. Compared with solid steel such as round steel, alloy steel pipe is lighter when the bending and torsional strength is the same. Alloy steel pipe is an economical cross-section steel, which is widely used to manufacture structural parts and mechanical parts, such as petroleum drill rods and automobile transmission Axles, bicycle frames, and steel scaffolding used in building construction. Manufacture of annular parts with alloy steel pipes can improve the utilization rate of materials, simplify the manufacturing process, save materials and processing hours, such as rolling bearing rings, jack sleeves, etc. Currently, steel pipes have been widely used for manufacturing. Alloy steel pipe is also an indispensable material for various conventional weapons. Gun barrels, barrels, etc. must be made of steel pipes. Alloy steel pipes can be divided into round pipes and special-shaped pipes according to the different cross-sectional area shapes. Since the circular area is the largest under the condition of equal perimeter, more fluid can be transported by the circular tube. In addition, when the cross section of the ring is subjected to internal or external radial pressure, the force is more uniform. Therefore, most steel pipes are round pipes.
Alloy pipes include large-diameter alloy pipes, thick-walled alloy pipes, high-pressure alloy pipes, alloy flanges, alloy elbows, P91 alloy pipes, and seamless steel pipes. In addition, special fertilizer pipes are also very common.